|
|Section2= |Section3= |Section7= |Section8= }} Tetrathiafulvalene is an organosulfur compound with the formula (H2C2S2C)2. Studies on this heterocyclic compound contributed to the development of molecular electronics. TTF is related to the hydrocarbon fulvalene, (C5H4)2, by replacement of four CH groups with sulfur atoms. Over 10,000 scientific publications discuss TTF and its derivatives. ==Preparation== The high level of interest in TTFs has spawned the development of many syntheses of TTF and its analogues.〔 Most preparations entail the coupling of cyclic C3S2 building blocks such as 1,3-dithiole-2-thiones or the related 1,3-dithiole-2-ones. For TTF itself, the synthesis begins with the trithiocarbonate H2C2S2CS, which is S-methylated and then reduced to give H2C2S2CH(SCH3), which is treated as follows: : + → + :2 + 2 → + 2 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Tetrathiafulvalene」の詳細全文を読む スポンサード リンク
|